Key of Symbols
? Magnetic material (requires special sputter source)
‡ One run only
* Influenced by composition
** The z-ratio is unknown. Therefore, we recommend using 1.00 or an experimentally
determined value. Please click here for instructions on how to determine this value.
*** All metals alumina coated
C = carbon | Ex = excellent | PDC = Pulsed DC sputtering |
Gr = graphite | G = good | RF = RF sputtering is effective |
Q = quartz | F = fair | RF-R = reactive RF sputter is effective |
Incl = Inconel® | P = poor | DC = DC sputtering is effective |
VitC = vitreous carbon | S = sublimes | DC-R = reactive DC sputtering is effective |
SS = stainless steel | D = decomposes |
Material | Symbol | Melting Point(°C) |
Density g/cm3 |
Temp.(°C) for Given Vap. Press. (Torr) | E-Beam Evaporation | Thermal Evaporation | Sputter | Comments | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
10-6 | 10-4 | 10-2 | Suitability | Liner Material | Boat | Coil | Basket | Crucible | ||||||
Aluminum Arsenide | AlAs | 1600 | 3.7 | - | ~1,300 | - | - | - | - | - | - | - | RF | - |
Aluminum Bromide | AlBr3 | 97 | 2.64 | - | - | ~50 | - | - | Mo | - | - | Gr | - | - |
Aluminum Carbide | Al4C3 | ~1,400 | 2.36 | - | - | ~800 | Fair | - | - | - | - | - | RF | - |
Aluminum Fluoride | AlF3 | 1291 | 2.88 | 410 | 490 | 700 | Poor | Graphite, Fabmate® | Mo, W, Ta | - | - | Gr | RF | - |
Aluminum Nitride | AlN | >2,200 | 3.26 | - | - | ~1750 | Fair | - | - | - | - | - | RF-R | Decomposes. Reactive evap in 10-3 T N2 with glow discharge. |
Aluminum Oxide | Al 2O 3 | >2,072 | 3.97 | - | - | 1550 | Excellent | Fabmate®, Tungsten | W | - | W | - | RF-R | Sapphire excellent in E-beam; forms smooth, hard films. |
Aluminum Phosphide | AlP | >2,000 | 2.42 | - | - | - | - | - | - | - | - | - | RF | - |
Aluminum, 1% Coppe | Al/Cu 99/1 wt% | >640 | 2.82 | - | - | - | - | - | - | - | - | - | DC | Wire feed & flash. Difficult from dual sources. |
Aluminum, 1% Silicon | Al/Si 99/1 wt % | >640 | 2.69 | - | - | 1010 | Fair | - | - | - | - | TiB2-BN | RF, DC | Wire feed & flash. Difficult from dual sources. |
Antimony | Sb | 630 | 6.68 | 279 | 345 | 425 | Poor | - | Mo*** Ta*** | Mo, Ta | Mo, Ta | BN, C, Al 2O 3 | RF, DC | Evaporates well. |
Antimony Oxide | Sb 2O 3 | 656 | 5.2 | - | - | ~300 | Good | - | - | - | - | BN,Al 2O 3 | RF-R | Decomposes on W. |
Antimony Selenide | Sb 2Se 3 | 611 | - | - | - | - | - | Ta | - | - | C | RF | Stoichiometry variable. | |
Antimony Sulfide | Sb 2S 3 | >550 | 4064 | - | - | ~200 | Good | Molybdenum, Tantalum | Mo, Ta | - | Mo, Ta | Al 2O 3 | - | No decomposition |
Antimony Telluride | Sb 2Te 3 | >629 | 6.5 | - | - | 600 | - | - | - | - | - | C | RF | Decomposes over 750°C. |
Arsenic | As | >817 | 5.73 | 107 | 150 | 210 | Poor | Fabmate® | C | - | - | Al 2O 3 | - | Sublimes rapidly at low temp. Not recommended for sputtering. |
Arsenic Oxide | As 2O 3 | >312 | 3.74 | - | - | - | - | - | - | - | - | - | - | - |
Arsenic Selenide | As 2Se 3 | ~360 | 4.75 | - | - | - | - | - | - | - | - | Al 2O 3,Q | RF | - |
Arsenic Sulfide | As 2S 3 | 300 | 3.43 | - | - | ~400 | Fair | - | Mo | - | - | Al 2O 3,Q | RF | - |
Arsenic Telluride | As 2Te 3 | >362 | 6.5 | - | - | - | - | - | Flash | - | - | - | - | See JVST. 1973, 10:748 |
Barium | Ba | >725 | 3.51 | 545 | 627 | 735 | Fair | - | W,Ta,Mo | W | W | Metals | RF | Wets without alloying, reacts with ceramics. Not recommended for sputtering. |
Barium Chloride | BaCl 2 | 963 | 3.92 | - | - | ~650 | - | - | Ta,Mo | - | - | - | RF | Preheat gently to outgas. |
Barium Fluoride | BaF 2 | 1355 | 4.89 | - | - | ~700 | Good | Molybdenum | Mo | - | - | - | RF | - |
Barium Oxide | BaO | 1918 | 5.72 | - | - | ~1300 | Poor | - | - | - | - | Al 2O 3 | RF,RF-R | Decomposes slightly. |
Barium Sulfide | BaS | 1200 | 4.25 | - | - | 1100 | - | - | Mo | - | - | - | RF | - |
Barium Titanate | BaTiO 3 | 1625 | 6.02 | - | - | - | - | - | - | - | - | - | RF | Gives Ba. Co-evap and Sputter OK. |
Beryllium | Be | 1278 | 1.85 | 710 | 878 | 1000 | Excellent | Graphite, Fabmate® | W,Ta | W | W | C | DC | Wets W/Mo/Ta. Evaporates easily |
Beryllium Carbide | Be 2C | >2100 | 1.9 | - | - | - | - | - | - | - | - | - | - | - |
Beryllium Chloride | BeCl2 | 405 | 1.9 | - | - | ~150 | - | - | - | - | - | - | RF | - |
Beryllium Fluoride | BeF2 | 800 | 1.99 | - | - | ~200 | Good | - | - | - | - | - | - | - |
Beryllium Oxide | BeO | 2530 | 3.01 | - | - | 1900 | Good | - | - | - | W | - | RF,RF-R | No decomposition from E-beam guns. |
Bismuth | Bi | 271 | 9.8 | 330 | 410 | 520 | Excellent | Fabmate®, Graphite | W, Mo, Ta | W | W | Al 2O 3 | DC | Resistivity high. Low Melting Point materials not ideal for sputtering. |
Bismuth Fluoride | BiF3 | 727 | 5.32 | - | - | ~300 | - | - | - | - | - | Gr | RF | - |
Bismuth Oxide | Bi2O3 | 860 | 8.55 | - | - | ~1400 | Poor | - | - | - | - | - | RF,RF-R | - |
Bismuth Selenide | Bi 2Se3 | 710 | 6.82 | - | - | ~650 | Good | - | - | - | - | Gr,Q | RF | Co-evap from 2 sources or sputter. |
Bismuth Sulfide | Bi 2S3 | 685 | 7.39 | - | - | - | - | - | - | - | - | - | RF | - |
Bismuth Telluride | Bi 2Te3 | 573 | 7.7 | - | - | ~600 | - | - | W,Mo | - | - | Gr,Q | RF | Co-evap from 2 sources or sputter. |
Bismuth Titanate | Bi 2Ti 2O 7 | 870 | - | - | - | - | - | - | - | - | - | - | RF | Sputter or co-evap from 2 sources in 10-2 Torr O2. |
Boron | B | 2079 | 2.34 | 1278 | 1548 | 1797 | Excellent | Fabmate®, Graphite | C | - | - | C | RF | Explodes with rapid cooling. Forms carbide with container. |
Boron Carbide | B 4C3 | 2350 | 2.52 | 2500 | 2580 | 2650 | Excellent | Fabmate®, Graphite | - | - | - | - | RF | Similar to chromium. |
Boron Nitride | BN | ~3000 | 2.25 | - | - | ~1600 | Poor | - | - | - | - | - | RF,RF-R | Decomposes when sputtered. Reactive preferred. |
Boron Oxide | B 2O3 | ~450 | 1.81 | - | - | ~1400 | Good | Molybdenum | Mo | - | - | - | - | - |
Boron Sulfide | B 2S3 | 310 | 1.55 | - | - | 800 | - | - | - | - | - | Gr | RF | - |
Cadmium | Cd | 321 | 8.64 | 64 | 120 | 180 | Poor | - | W,Mo,Ta | - | W,Mo,Ta | Al 2O 3,Q | DC,RF | Bad for vacuum systems. Low sticking coefficient. |
Cadmium Antimonide | Cd3Sb 2 | 456 | 6.92 | - | - | - | - | - | - | - | - | - | - | - |
Cadmium Arsenide | Cd3As 2 | 721 | 6.21 | - | - | - | - | - | - | - | - | Q | RF | - |
Cadmium Bromide | CdBr2 | 567 | 5.19 | - | - | ~300 | - | - | - | - | - | - | - | - |
Cadmium Chloride | CdCl2 | 568 | 4.05 | - | - | ~400 | - | - | - | - | - | - | - | - |
Cadmium Fluoride | CdF2 | 1100 | 6.64 | - | - | ~500 | - | - | - | - | - | - | RF | - |
Cadmium Iodide | CdI2 | 387 | 5.67 | - | - | ~250 | - | - | - | - | - | - | - | - |
Cadmium Oxide | CdO | >1500 | 6.95 | - | - | ~530 | - | - | - | - | - | - | RF-R | Disproportionates. |
Cadmium Selenide | CdSe | >1350 | 5.81 | - | - | 540 | Good | Molybdenum, Tantalum | Mo, Ta | - | - | Al 2O 3,Q | RF | Evaporates easily. |
Cadmium Sulfide | CdS | 1750 | 4.82 | - | - | 550 | Fair | - | W,Mo,Ta | - | W | Al 2O 3,Q | RF | Sticking coefficient affected by substrate. |
Cadmium Telluride | CdTe | 1092 | 5.85 | - | - | 450 | - | - | W,Mo,Ta | W | W,Ta,Mo | - | RF | Stoichiometry depends on substrate temp. n~2.6. |
Calcium | Ca | 839 | 1.54 | 272 | 357 | 459 | Poor | - | W | W | W | Al2O3, Q | - | Corrodes in air. |
Calcium Silicate | CaSiO3 | 1540 | 2.91 | - | - | - | Good | - | - | - | - | Q | RF | - |
Calcium Tungstate | CaWO4 | 1200 | 6.06 | - | - | - | Good | - | W | - | - | - | RF | - |
Cerium (III) Oxide | Ce2O3 | 1692 | 6.86 | - | - | - | Fair | - | W | - | - | - | - | Alloys with source. Use 0.015"–0.020" W boat. |
Cerium (IV) Oxide | CeO2 | ~2,600 | 7.13 | 1890 | 2000 | 2310 | Good | Tantalum, Graphite, Fabmate® | W | - | - | - | RF, RF-R | Very little decomposition. |
Cerium Fluoride | CeF3 | 1460 | 6.16 | - | - | ~900 | Good | Tungsten, Tantalum, Molybdenum | W, Mo, Ta | - | Mo, Ta | - | RF | Preheat gently to outgas. n~1.7. |
Cesium | Cs | 28 | 1.88 | -16 | 22 | 80 | - | - | - | - | - | Q | - | - |
Cesium Bromide | CsBr | 636 | 3.04 | - | - | ~400 | - | - | W | - | - | - | RF | - |
Cesium Chloride | CsCl | 645 | 3.99 | - | - | ~500 | - | - | W | - | - | - | RF | - |
Cesium Fluoride | CsF | 682 | 4.12 | - | - | ~500 | - | - | W | - | - | - | RF | - |
Cesium Hydroxide | CsOH | 272 | 3.68 | - | - | 550 | - | - | - | - | - | - | - | - |
Cesium Iodide | CsI | 626 | 4.51 | - | - | ~500 | - | - | W | - | - | Q | RF | - |
Chiolite | Na5Al3F14 | 735 | 2.9 | - | - | ~800 | - | - | Mo, W | - | - | - | RF | - |
Chromium | Cr | 1857 | 7.2 | 837 | 977 | 1157 | Good | Fabmate®, Graphite, Tungsten | Cr Plated W Rods | W | W | VitC | DC | Films very adherent. High rates possible. |
Chromium Boride | CrB | 1,950-2,050 | 6.17 | - | - | - | - | - | - | - | - | - | RF | - |
Chromium (II) Bromide | CrBr2 | 842 | 4.36 | - | - | 550 | - | - | - | - | - | - | RF | - |
Chromium Carbide | Cr3C2 | 1895 | 6.68 | - | - | ~2,000 | Fair | - | W | - | - | - | RF | - |
Chromium Chloride | CrCl2 | 824 | 2.88 | - | - | 550 | - | - | Fe | - | - | - | RF | - |
Chromium Oxide | Cr2O3 | 2266 | 5.21 | - | - | ~2,000 | Good | - | W, Mo | - | W | - | RF, RF-R | Disproportionates to lower oxides; reoxidizes at 600°C in air. |
Chromium Silicide | CrSi2 | 1490 | 5.5 | - | - | - | - | - | - | - | - | - | RF | - |
Chromium-Silicon Monoxide | Cr-SiO | - | * | * | * | * | Good | - | W | - | W | - | RF | Flash evaporate. |
Cobalt † | Co | 1495 | 8.9 | 850 | 990 | 1200 | Excellent | Direct in Hearth | W, Nb | - | W | Al2O3 | DC | Alloys with W/Ta/Mo. |
Cobalt Bromide | CoBr2 | 678 | 4.91 | - | - | 400 | - | - | - | - | - | - | RF | - |
Cobalt Chloride | CoCl2 | 724 | 3.36 | - | - | 472 | - | - | - | - | - | - | RF | - |
Cobalt Oxide | CoO | 1795 | 6.45 | - | - | - | - | - | - | - | - | - | DC-R, RF-R | Sputtering preferred. |
Copper | Cu | 1083 | 8.92 | 727 | 857 | 1017 | Excellent | Graphite, Molybdenum | Mo, W | W | W | Al2O3, Mo, Ta | DC | Adhesion poor. Use interlayer (Cr). Evaporates using any source material. |
Copper Chloride | CuCl | 430 | 4.14 | - | - | ~600 | - | - | - | - | - | - | RF | - |
Copper Oxide | Cu2O | 1235 | 6 | - | - | ~600 | Good | Graphite, Fabmate®, Tantalum | Ta | - | - | Al2O3 | DC-R, RF-R | - |
Copper Sulfide | Cu2S | 1100 | 5.6 | - | - | - | - | - | - | - | - | - | - | - |
Cryolite | Na3AlF6 | 1000 | 2.9 | 1020 | 1260 | 1480 | Excellent | Fabmate®, Tungsten | W, Mo, Ta | - | W, Mo, Ta | VitC | RF | Large chunks reduce spitting. Little decomposition. |
Dysprosium | Dy | 1412 | 8.55 | 625 | 750 | 900 | Good | Direct in Hearth | Ta | - | - | - | DC | - |
Dysprosium Fluoride | DyF3 | 1360 | - | - | - | ~800 | Good | - | Ta | - | - | - | RF | - |
Dysprosium Oxide | Dy2O3 | 2340 | 7.81 | - | - | ~1,400 | - | - | - | - | - | - | RF, RF-R | Loses oxygen. |
Erbium | Er | 1529 | 9.07 | 650 | 775 | 930 | Good | Tungsten, Tantalum | W, Ta | - | - | - | DC | - |
Erbium Fluoride | ErF3 | 1350 | 7.82 | - | - | ~750 | - | - | Mo | - | - | - | RF | See JVST. 1985; A3(6):2320. |
Erbium Oxide | Er2O3 | 2350 | 8.64 | - | - | ~1,600 | - | - | - | - | - | - | RF, RF-R | Loses oxygen. |
Europium | Eu | 822 | 5.24 | 280 | 360 | 480 | Fair | - | W, Ta | - | - | Al2O3 | DC | Low Ta solubility. |
Europium Fluoride | EuF2 | 1380 | 6.5 | - | - | ~950 | - | - | Mo | - | - | - | RF | - |
Europium Oxide | Eu2O3 | 2350 | 7.42 | - | - | ~1,600 | Good | - | Ta, W | - | - | ThO2 | RF, RF-R | Loses oxygen. Films clear and hard. |
Europium Sulfide | EuS | - | 5.75 | - | - | - | Good | - | - | - | - | - | RF | - |
Gadolinium † | Gd | 1313 | 7.9 | 760 | 900 | 1175 | Excellent | Direct in Hearth | Ta | - | - | Al2O3 | DC | High Ta solubility |
Gadolinium Carbide | GdC2 | - | - | - | - | 1500 | - | - | - | - | - | C | RF | Decomposes under sputtering. |
Gadolinium Oxide | Gd2O3 | 2330 | 7.41 | - | - | - | Fair | - | - | - | - | - | RF, RF-R | Loses oxygen. |
Gallium | Ga | 30 | 5.9 | 619 | 742 | 907 | Good | Fabmate® | - | - | - | Al2O3, Q | - | Alloys with W/Ta/Mo. Use E-beam gun. Low Melting Point materials not ideal for sputtering. |
Gallium Antimonide | GaSb | 710 | 5.6 | - | - | - | Fair | - | W, Ta | - | - | - | RF | Flash evaporate. |
Gallium Arsenide | GaAs | 1238 | 5.3 | - | - | - | Good | Graphite, Fabmate® | W, Ta | - | - | C | RF | Flash evaporate. |
Gallium Nitride | GaN | 800 | 6.1 | - | - | ~200 | - | - | - | - | - | Al2O3 | RF, RF-R | Evaporate Ga in 10-3Torr N2. |
Gallium Oxide | Ga2O3 | 1900 | 6.44 | - | - | - | - | - | W | - | - | - | RF | Loses oxygen. |
Gallium Phosphide | GaP | 1540 | 4.1 | - | 770 | 920 | - | - | W, Ta | - | W | Q | RF | Does not decompose. Rate control important. |
Germanium | Ge (N-type) | 937 | 5.35 | 812 | 957 | 1167 | Excellent | Fabmate®, Graphite | W, C, Ta | - | - | Q, Al2O3 | DC | Excellent films from E-beam. |
Germanium (II) Oxide | GeO | 700 | - | - | - | 500 | - | - | - | - | - | Q | RF | - |
Germanium (III) Oxide | GeO2 | 1086 | 6.24 | - | - | ~625 | Good | Fabmate®, Tantalum, Molybdenum | Ta, Mo | - | W, Mo | Q, Al2O3 | RF-R | Similar to SiO; film predominantly GeO. |
Germanium Nitride | Ge3N2 | 450 | 5.2 | - | - | ~650 | - | - | - | - | - | - | RF-R | Sputtering preferred. |
Germanium Telluride | GeTe | 725 | 6.2 | - | - | 381 | - | - | W, Mo | - | W | Q, Al2O3 | RF | - |
Glass, Schott® 8329 | — | 1300 | 2.2 | - | - | - | Excellent | - | - | - | - | - | RF | Evaporable alkali glass. Melt in air before evaporating. |
Gold | Au | 1064 | 19.32 | 807 | 947 | 1132 | Excellent | Fabmate®, Molybdenum | W*** Mo*** W | - | - | Al2O3, BN | DC | Films soft; not very adherent. |
Hafnium | Hf | 2227 | 13.31 | 2160 | 2250 | 3090 | Good | - | - | - | - | - | DC | - |
Hafnium Boride | HfB2 | 3250 | 10.5 | - | - | - | - | - | - | - | - | - | DC, RF | - |
Hafnium Carbide | HfC | ~3,890 | 12.2 | - | - | ~2,600 | - | - | - | - | - | - | RF | - |
Hafnium Nitride | HfN | 3305 | 13.8 | - | - | - | - | - | - | - | - | - | RF, RF-R | - |
Hafnium Oxide | HfO2 | 2758 | 9.68 | - | - | ~2,500 | Fair | Direct in Hearth | - | - | - | - | RF, RF-R | Film HfO. |
Hafnium Silicide | HfSi2 | 1750 | 7.2 | - | - | - | - | - | - | - | - | - | RF | - |
Holmium | Ho | 1474 | 8.8 | 650 | 770 | 950 | Good | - | W, Ta | W | W | - | - | - |
Holmium Fluoride | HoF3 | 1143 | 7.68 | - | - | ~800 | - | - | - | - | - | Q | DC, RF | - |
Holmium Oxide | Ho2O3 | 2370 | 8.41 | - | - | - | - | - | - | - | - | - | RF, RF-R | Loses oxygen. |
Inconel® | Ni/Cr/Fe | 1425 | 8.5 | - | - | - | Good | Fabmate®, Tungsten | W | W | W | - | DC | Use fine wire wrapped on W. Low rate required for smooth films. |
Indium | In | 157 | 7.3 | 487 | 597 | 742 | Excellent | Fabmate®, Graphite, Molybdenum | W, Mo | - | W | Gr, Al2O3 | DC | Wets W and Cu. Use Mo liner. Low Melting Point materials not ideal for sputtering. |
Indium (I) Oxide | In2O | ~600 | 6.99 | - | - | 650 | - | - | - | - | - | - | RF | Decomposes under sputtering. |
Indium (III) Oxide | In2O3 | 850 | 7.18 | - | - | ~1,200 | Good | - | W, Pt | - | - | Al2O3 | - | - |
Indium (I) Sulfide | In2S | 653 | 5.87 | - | - | 650 | - | - | - | - | - | Gr | RF | - |
Indium (II) Sulfide | InS | 692 | 5.18 | - | - | 650 | - | - | - | - | - | Gr | RF | - |
Indium (III) Sulfide | In2S3 | 1050 | 4.9 | - | - | 850 | - | - | - | - | - | Gr | RF | Film In2S. |
Indium (II) Telluride | InTe | 696 | 6.29 | - | - | - | - | - | - | - | - | - | - | - |
Indium (III) Telluride | In2Te3 | 667 | 5.78 | - | - | - | - | - | - | - | - | - | RF | Sputtering preferred; or co-evaporate from 2 sources; flash. |
Indium Antimonide | InSb | 535 | 5.8 | - | - | - | - | - | W | - | - | - | RF | Decomposes. Sputtering preferred; or co-evaporate. |
Indium Arsenide | InAs | 943 | 5.7 | 780 | 870 | 970 | - | - | W | - | - | - | RF | - |
Indium Nitride | InN | 1200 | 7 | - | - | - | - | - | - | - | - | - | - | - |
Indium Phosphide | InP | 1070 | 4.8 | - | 630 | 730 | - | - | W, Ta | - | W, Ta | Gr | RF | Deposits are P rich. |
Indium Selenide | In2Se3 | 890 | 5.67 | - | - | - | - | - | - | - | - | - | RF | Sputtering preferred; or co-evaporate from 2 sources; flash. |
Indium Tin Oxide | In2O3/SnO290/10 wt % |